Issue 20, 2007
From the journal:

Chemical Communications

The first trialkylphosphane telluride complexes of Ag(i): molecular, ionic and supramolecular structural alternatives

Constantin Daniliuc,a   Christian Druckenbrodt,a   Cristian G. Hrib,a   Frank Ruthe,a   Armand Blaschette,a   Peter G. Jonesa  and  Wolf-W. du Mont*a  

* Corresponding authors

a Institut für Anorg. u. Analyt. Chemie der Technischen Universität Braunschweig, Postfach 3329, Germany
E-mail: w.du-mont@tu-bs.de

Abstract

The structures of the first phosphane telluride complexes of silver(I), obtained from i-Pr3PTe (1) with AgNMs2 [Ms = SO2CH3] and with AgSbF6, reveal the superior coordinating ability of 1, particularly as a bridging ligand, compared with related i-Pr3PS and i-Pr3PSe ligands.

Graphical abstract: The first trialkylphosphane telluride complexes of Ag(i): molecular, ionic and supramolecular structural alternatives

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Article information

DOI
https://doi.org/10.1039/B700917H
Article type
Communication
Submitted
22 Jan 2007
Accepted
14 Mar 2007
First published
11 Apr 2007

Chem. Commun., 2007, 2060-2062

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The first trialkylphosphane telluride complexes of Ag(I): molecular, ionic and supramolecular structural alternatives

C. Daniliuc, C. Druckenbrodt, C. G. Hrib, F. Ruthe, A. Blaschette, P. G. Jones and Wolf-W. du Mont, Chem. Commun., 2007, 2060 DOI: 10.1039/B700917H

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