Microsystem controlled cationic polymerization of vinyl ethers initiated by CF3SO3H

Takeshi Iwasaki; Aiichiro Nagaki; Jun-ichi Yoshida

doi:10.1039/B615159K

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Microsystem controlled cationic polymerization of vinyl ethers initiated by CF₃SO₃H†

Takeshi Iwasaki,^a Aiichiro Nagaki^b and Jun-ichi Yoshida*^b

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* Corresponding authors

^a Central Research Laboratories, Idemitsu Kosan Co. Ltd., 1280 Kami-izumi, Sodegaura, Japan

^b Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Japan
E-mail: yoshida@sbchem.kyoto-u.ac.jp
Fax: +81-75-383-2727
Tel: +81-75-383-2726

Abstract

Practical cationic polymerization and block-copolymerization of vinyl ethers have been achieved at −25 °C by using CF₃SO₃H initiator in microsystems with high level of molecular weight distribution control.

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Experimental PDF (256K)

Article information

DOI: https://doi.org/10.1039/B615159K
Article type: Communication
Submitted: 18 Oct 2006
Accepted: 14 Dec 2006
First published: 11 Jan 2007

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Chem. Commun., 2007, 1263-1265

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Microsystem controlled cationic polymerization of vinyl ethers initiated by CF₃SO₃H

T. Iwasaki, A. Nagaki and J. Yoshida, Chem. Commun., 2007, 1263 DOI: 10.1039/B615159K

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