Issue 7, 2007
From the journal:

Chemical Communications

Investigating organocatalytic reactions: mass spectrometric studies of a conjugate umpolung reaction

Wolfgang Schrader,*a   Peni Purwa Handayani,a   Christian Bursteinb  and  Frank Gloriusb  

* Corresponding authors

a Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, Mülheim an der Ruhr, Germany
E-mail: wschrader@mpi-muelheim.mpg.de
Fax: ++49 208 3062271

b Philipps-Universität Marburg, Fachbereich Chemie, Hans-Meerwein-Straße, Marburg, Germany

Abstract

An organocatalyzed conjugate umpolung reaction has been studied in detail using electrospray mass spectrometry, which allows to support the catalytic cycle by intercepting intermediates.

Graphical abstract: Investigating organocatalytic reactions: mass spectrometric studies of a conjugate umpolung reaction

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Article information

DOI
https://doi.org/10.1039/B613862D
Article type
Communication
Submitted
25 Sep 2006
Accepted
14 Nov 2006
First published
07 Dec 2006

Chem. Commun., 2007, 716-718

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Investigating organocatalytic reactions: mass spectrometric studies of a conjugate umpolung reaction

W. Schrader, P. P. Handayani, C. Burstein and F. Glorius, Chem. Commun., 2007, 716 DOI: 10.1039/B613862D

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