Issue 8, 2007

A tetradecanuclear copper dimeric macrocyclic complex with a body-centred heptanuclear core-structure and magnetism

Abstract

2,6-Diformyl-4-methylphenol and 1,3-diamino-2-hydroxypropane template condense in the presence of Cu(NO3)2 and azide to produce a 3 : 3 macrocyclic ring containing an unprecedented grouping of seven copper(II) ions within the macrocyclic cavity, with the seventh metal completing a body-centred heptanuclear lattice.

Graphical abstract: A tetradecanuclear copper dimeric macrocyclic complex with a body-centred heptanuclear core-structure and magnetism

Supplementary files

Article information

Article type
Communication
Submitted
05 Sep 2006
Accepted
01 Nov 2006
First published
23 Nov 2006

Chem. Commun., 2007, 798-800

A tetradecanuclear copper dimeric macrocyclic complex with a body-centred heptanuclear core-structure and magnetism

S. S. Tandon, S. D. Bunge and L. K. Thompson, Chem. Commun., 2007, 798 DOI: 10.1039/B612795A

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