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Issue 2, 2007
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{Ge10Si[Si(SiMe3)3]4(SiMe3)2Me}: A Ge10Si framework reveals a structural transition onto elemental germanium

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Abstract

The reaction of the metastable high temperature molecule GeCl synthesized via a co-condensation technique with LiSi(SiMe3)3 leads to a metalloid Ge10Si cluster compound, in which the arrangement of the germanium atoms can be seen as a cutout from the structure of elemental germanium.

Graphical abstract: {Ge10Si[Si(SiMe3)3]4(SiMe3)2Me}−: A Ge10Si framework reveals a structural transition onto elemental germanium

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Publication details

The article was received on 02 Aug 2006, accepted on 28 Sep 2006 and first published on 24 Oct 2006


Article type: Communication
DOI: 10.1039/B611165C
Chem. Commun., 2007, 192-194

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    {Ge10Si[Si(SiMe3)3]4(SiMe3)2Me}: A Ge10Si framework reveals a structural transition onto elemental germanium

    A. Schnepf, Chem. Commun., 2007, 192
    DOI: 10.1039/B611165C

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