X-Ray photoreduction of a di(μ-oxo)MnIIIMnIV complex occurs at temperatures as low as 20 K

Lionel Dubois; Lilian Jacquamet; Jacques Pécaut; Jean-Marc Latour

doi:10.1039/B609072A

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X-Ray photoreduction of a di(μ-oxo)MnⁱⁱⁱMn^iv complex occurs at temperatures as low as 20 K†

Lionel Dubois,^ac Lilian Jacquamet,^b Jacques Pécaut^c and Jean-Marc Latour*^a

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* Corresponding authors

^a Laboratoire DRDC/PMB, UMR 5155 CEA-CNRS-UJF, CEA-Grenoble, France
E-mail: Jean-Marc.Latour@cea.fr
Fax: +33 438 78 34 62
Tel: +33 438 78 44 07

^b Laboratoire LCCP, IBS, UMR 5075 CEA-CNRS-UJF, France

^c Laboratoire LCIB, UMR E, CEA-Grenoble, France

Abstract

Full reduction of the Mn^III(μ-O)₂Mn^IV core to Mn^II(μ-OH₂)₂Mn^II is observed upon irradiation by an X-ray beam at ca. 20 K.

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Article information

DOI: https://doi.org/10.1039/B609072A
Article type: Communication
Submitted: 27 Jun 2006
Accepted: 30 Aug 2006
First published: 18 Sep 2006

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Chem. Commun., 2006, 4521-4523

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X-Ray photoreduction of a di(μ-oxo)Mn^IIIMn^IV complex occurs at temperatures as low as 20 K

L. Dubois, L. Jacquamet, J. Pécaut and J. Latour, Chem. Commun., 2006, 4521 DOI: 10.1039/B609072A

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