Issue 39, 2006

Direct synthesis of 1,1-diarylalkenes from alkenyl phosphatesvia nickel(0)-catalysed Suzuki–Miyaura coupling

Abstract

A combination of Ni(COD)2 and PCy3 promotes effectively the Suzuki–Miyaura cross coupling of 1-arylalkenyl phosphates with aryl boronic acids with yields attaining 99%.

Graphical abstract: Direct synthesis of 1,1-diarylalkenes from alkenyl phosphates via nickel(0)-catalysed Suzuki–Miyaura coupling

Supplementary files

Article information

Article type
Communication
Submitted
26 Jun 2006
Accepted
09 Aug 2006
First published
22 Aug 2006

Chem. Commun., 2006, 4137-4139

Direct synthesis of 1,1-diarylalkenes from alkenyl phosphates via nickel(0)-catalysed Suzuki–Miyaura coupling

A. L. Hansen, J. Ebran, T. M. Gøgsig and T. Skrydstrup, Chem. Commun., 2006, 4137 DOI: 10.1039/B609064H

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