Issue 39, 2006
From the journal:

Chemical Communications

Unprecedented intermolecular C–H bond activation of a solventtoluene molecule leading to a seven-membered platinacycle†

Alejandro Capapé,a   Margarita Crespo,*a   Jaume Granell,*a   Albert Vizcarro,a   Javier Zafrilla,a   Mercè Font-Bardíab  and  Xavier Solansb  

* Corresponding authors

a Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 647, Barcelona, Spain
E-mail: margarita.crespo@qi.ub.es
Fax: 34934907725
Tel: 34934039132

b Department de Cristal·lografia, Mineralogia i Deposits Minerals Universitat de Barcelona, Martí i Franquès s/n, Barcelona, Spain

Abstract

A novel platinum-mediated process involving intermolecular activation of a Caryl–H bond of toluene, intramolecular activation of an imine Caryl–Cl bond and formation of a C–C bond is reported.

Graphical abstract: Unprecedented intermolecular C–H bond activation of a solvent toluene molecule leading to a seven-membered platinacycle

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Article information

DOI
https://doi.org/10.1039/B608666G
Article type
Communication
Submitted
21 Jun 2006
Accepted
04 Aug 2006
First published
22 Aug 2006

Chem. Commun., 2006, 4128-4130

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Unprecedented intermolecular C–H bond activation of a solvent toluene molecule leading to a seven-membered platinacycle

A. Capapé, M. Crespo, J. Granell, A. Vizcarro, J. Zafrilla, M. Font-Bardía and X. Solans, Chem. Commun., 2006, 4128 DOI: 10.1039/B608666G

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