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Issue 39, 2006
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Unprecedented intermolecular C–H bond activation of a solventtoluene molecule leading to a seven-membered platinacycle

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Abstract

A novel platinum-mediated process involving intermolecular activation of a Caryl–H bond of toluene, intramolecular activation of an imine Caryl–Cl bond and formation of a C–C bond is reported.

Graphical abstract: Unprecedented intermolecular C–H bond activation of a solvent toluene molecule leading to a seven-membered platinacycle

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Article information


Submitted
21 Jun 2006
Accepted
04 Aug 2006
First published
22 Aug 2006

Chem. Commun., 2006, 4128-4130
Article type
Communication

Unprecedented intermolecular C–H bond activation of a solvent toluene molecule leading to a seven-membered platinacycle

A. Capapé, M. Crespo, J. Granell, A. Vizcarro, J. Zafrilla, M. Font-Bardía and X. Solans, Chem. Commun., 2006, 4128
DOI: 10.1039/B608666G

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