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Issue 46, 2006
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Stereoselective formation of a single-stranded helicate: Structure of a bis(palladium-allyl)quaterpyridine complex and its use in catalytic enantioselective allylic substitution

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Abstract

Chiral C2-symmetric quaterpyridine L reacts with [Pd(η3-C3H5)Cl]2 to form a chiral single-stranded helical binuclear palladium complex of formula [Pd23-C3H5)2(L)]2+; the complex can efficiently catalyze allylic substitution of 1,3-diphenylprop-2-enyl acetate with dimethyl malonate with enantioselectivity up to 85%.

Graphical abstract: Stereoselective formation of a single-stranded helicate: Structure of a bis(palladium-allyl)quaterpyridine complex and its use in catalytic enantioselective allylic substitution

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Publication details

The article was received on 15 Jun 2006, accepted on 18 Sep 2006 and first published on 04 Oct 2006


Article type: Communication
DOI: 10.1039/B608481H
Citation: Chem. Commun., 2006,0, 4841-4843
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    Stereoselective formation of a single-stranded helicate: Structure of a bis(palladium-allyl)quaterpyridine complex and its use in catalytic enantioselective allylic substitution

    H. Kwong, H. Yeung, W. Lee and W. Wong, Chem. Commun., 2006, 0, 4841
    DOI: 10.1039/B608481H

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