Issue 39, 2006

[Znn(polyox)(pmtz)n]: the first polyoxalate-containing coordination polymer from an unforeseen chemical rearrangement of 5-pyrimidyl-tetrazole under hydrothermal conditions

Abstract

The compound [Zn2(polyox)(pmtz)2], which has been prepared by the hydrothermal reaction of ZnCl2 and Napmtz (5-pyrimidyl-tetrazolate), exhibits a unique 2D network with (6,3) topology, in which ZnII ions are connected by pmtz- and polyoxalate-bridging ligands (generated in situ from the breaking of the pmzt ligand). This is the first structural report on a polyoxalate species.

Graphical abstract: [Znn(polyox)(pmtz)n]: the first polyoxalate-containing coordination polymer from an unforeseen chemical rearrangement of 5-pyrimidyl-tetrazole under hydrothermal conditions

Supplementary files

Article information

Article type
Communication
Submitted
14 Jun 2006
Accepted
31 Jul 2006
First published
21 Aug 2006

Chem. Commun., 2006, 4140-4142

[Znn(polyox)(pmtz)n]: the first polyoxalate-containing coordination polymer from an unforeseen chemical rearrangement of 5-pyrimidyl-tetrazole under hydrothermal conditions

A. Rodríguez-Diéguez and E. Colacio, Chem. Commun., 2006, 4140 DOI: 10.1039/B608403F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements