[Znn(polyox)(pmtz)n]: the first polyoxalate-containing coordination polymer from an unforeseen chemical rearrangement of 5-pyrimidyl-tetrazole under hydrothermal conditions
Abstract
The compound [Zn2(polyox)(pmtz)2], which has been prepared by the hydrothermal reaction of ZnCl2 and Napmtz (5-pyrimidyl-tetrazolate), exhibits a unique 2D network with (6,3) topology, in which ZnII ions are connected by pmtz- and polyoxalate-bridging