Issue 35, 2006

Self-assembly of a bis-porphyrinic supramolecular rectangle using two orthogonal binding strategies

Abstract

A bis-porphyrinic rectangle is created via a double self-assembly algorithm using two orthogonal coordination themes, i.e. first a 90° building block composed of a dynamic heteroleptic Cu(I) or Ag(I) bisphenanthroline followed by a coordinative dimerization using the pyridinezinc porphyrin motif; the spectroscopic and electrochemical properties as well as the dynamic nature of the supramolecule were tested.

Graphical abstract: Self-assembly of a bis-porphyrinic supramolecular rectangle using two orthogonal binding strategies

Supplementary files

Article information

Article type
Communication
Submitted
13 Jun 2006
Accepted
29 Jun 2006
First published
28 Jul 2006

Chem. Commun., 2006, 3690-3692

Self-assembly of a bis-porphyrinic supramolecular rectangle using two orthogonal binding strategies

R. S. K. Kishore, V. Kalsani and M. Schmittel, Chem. Commun., 2006, 3690 DOI: 10.1039/B608315C

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