Issue 41, 2006
From the journal:

Chemical Communications

Rhodium N-confused porphyrin-catalyzed alkene cyclopropanation

Teppei Niino,a   Motoki Toganoh,a   Bruno Andriolettib  and  Hiroyuki Furuta*ac  

* Corresponding authors

a Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Japan
E-mail: hfuruta@cstf.kyushu-u.ac.jp
Fax: +81 92-802-2865
Tel: +81 92-802-2865

b Université Pierre et Marie Curie-Paris 6, Laboratoire de Chimie Organique (UMR CNRS 7611), Institut de Chimie Moléculaire (FR 2769), case 181, 4 place Jussieu, France

c PRESTO, Japan Science and Technology Agency, 4-1-8 Honcho, Japan

Abstract

Rhodium N-confused porphyrins constitute unprecedented, highly efficient tools for the cyclopropanation of styrene, affording the expected cyclopropanes in excellent yields with trans : cis ratios reaching 98 : 2.

Graphical abstract: Rhodium N-confused porphyrin-catalyzed alkene cyclopropanation

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Article information

DOI
https://doi.org/10.1039/B608154A
Article type
Communication
Submitted
09 Jun 2006
Accepted
13 Aug 2006
First published
05 Sep 2006

Chem. Commun., 2006, 4335-4337

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Rhodium N-confused porphyrin-catalyzed alkene cyclopropanation

T. Niino, M. Toganoh, B. Andrioletti and H. Furuta, Chem. Commun., 2006, 4335 DOI: 10.1039/B608154A

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