Issue 43, 2006
From the journal:

Chemical Communications

Coordination of oxovanadium(v) in an expanded porphyrin macrocycle†

Jonathan L. Sessler,*a   Elisa Tomata  and  Vincent M. Lyncha  

* Corresponding authors

a Department of Chemistry and Biochemistry, 1 University Station, The University of Texas at Austin, Austin, TX, USA
E-mail: sessler@mail.utexas.edu
Fax: +1 512 471 7550
Tel: +1 512 471 5009

Abstract

The formation of a dioxovanadium(V) complex of an expanded porphyrin-type Schiff base macrocycle is reported; the tetrapyrrolic ligand undergoes a tautomeric shift which permits a bimodal recognition of the nonspherical cationic guest.

Graphical abstract: Coordination of oxovanadium(v) in an expanded porphyrin macrocycle

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Article information

DOI
https://doi.org/10.1039/B608143F
Article type
Communication
Submitted
08 Jun 2006
Accepted
25 Jul 2006
First published
02 Aug 2006

Chem. Commun., 2006, 4486-4488

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Coordination of oxovanadium(V) in an expanded porphyrin macrocycle

J. L. Sessler, E. Tomat and V. M. Lynch, Chem. Commun., 2006, 4486 DOI: 10.1039/B608143F

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