Jump to main content
Jump to site search

Issue 39, 2006
Previous Article Next Article

High pressure co-ordination chemistry of a palladium thioether complex: pressure versus electrons

Author affiliations

Abstract

The mononuclear Pd(II) complex cis-[PdCl2([9]aneS3)] ([9]aneS3 = 1,4,7-trithiacyclononane) converts at 44 kbar pressure into an intensely coloured chain polymer, which exhibits distorted octahedral co-ordination at the metal centre and an unprecedented [1233] conformation for the thioether crown.

Graphical abstract: High pressure co-ordination chemistry of a palladium thioether complex: pressure versus electrons

Back to tab navigation

Supplementary files

Publication details

The article was received on 12 May 2006, accepted on 20 Jun 2006 and first published on 06 Jul 2006


Article type: Communication
DOI: 10.1039/B606736K
Chem. Commun., 2006, 4081-4083

  •   Request permissions

    High pressure co-ordination chemistry of a palladium thioether complex: pressure versus electrons

    D. R. Allan, A. J. Blake, D. Huang, T. J. Prior and M. Schröder, Chem. Commun., 2006, 4081
    DOI: 10.1039/B606736K

Search articles by author

Spotlight

Advertisements