Galactose Oxidase models: 19F NMR as a powerful tool to study the solution chemistry of tripodal ligands in the presence of copper(II)

Fabien Michel; Sylvain Hamman; Fabrice Thomas; Christian Philouze; Isabelle Gautier-Luneau; Jean-Louis Pierre

doi:10.1039/B605852C

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Galactose Oxidase models: ¹⁹F NMR as a powerful tool to study the solution chemistry of tripodal ligands in the presence of copper(ii)†

Fabien Michel,^a Sylvain Hamman,^a Fabrice Thomas,*^a Christian Philouze,^a Isabelle Gautier-Luneau^b and Jean-Louis Pierre^a

Author affiliations

* Corresponding authors

^a Laboratoire d'Etudes Dynamiques et Structurales de la Sélectivité, Equipe de Chimie Biomimétique, UMR CNRS 5616, ICMG FR CNRS 2607, Université Joseph Fourier, BP 53, Grenoble cedex 9, France
E-mail: Fabrice.Thomas@ujf-grenoble.fr
Fax: +33 476 514 846
Tel: +33 476 514 373

^b Laboratoire de Cristallographie, CNRS, 25 avenue des Martyrs, BP 166, Grenoble Cedex 9, France

Abstract

In copper(II) complexes of tripodal ligands, the protonation state of the phenol moiety, and its position (axial vs. equatorial), are easily assessed by ¹⁹F NMR.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B605852C
Article type: Communication
Submitted: 06 Jun 2006
Accepted: 26 Jul 2006
First published: 22 Aug 2006

Download Citation

Chem. Commun., 2006, 4122-4124

Permissions

Request permissions

Galactose Oxidase models: ¹⁹F NMR as a powerful tool to study the solution chemistry of tripodal ligands in the presence of copper(II)

F. Michel, S. Hamman, F. Thomas, C. Philouze, I. Gautier-Luneau and J. Pierre, Chem. Commun., 2006, 4122 DOI: 10.1039/B605852C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications