Issue 23, 2006
From the journal:

Chemical Communications

Ortho-substituted iodobenzenes as novel organocatalysts for bromination of alkenes†

D. Christopher Braddock,*a   Gemma Cansella  and  Stephen A. Hermitageb  

* Corresponding authors

a Department of Chemistry, Imperial College London, London, UK
E-mail: c.braddock@imperial.ac.uk
Fax: +44(0)2075945805
Tel: +44(0)2075945772

b GlaxoSmithKline Ltd, Medicines Research Centre, Gunnels Wood Road, Stevenage, UK

Abstract

Suitably ortho-substituted iodobenzenes act as organocatalysts for the transfer of electrophilic bromine from N-bromosuccinimide to alkenes via the intermediacy of bromoiodinanes.

Graphical abstract: Ortho-substituted iodobenzenes as novel organocatalysts for bromination of alkenes

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Article information

DOI
https://doi.org/10.1039/B604130B
Article type
Communication
Submitted
21 Mar 2006
Accepted
20 Apr 2006
First published
03 May 2006

Chem. Commun., 2006, 2483-2485

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Ortho-substituted iodobenzenes as novel organocatalysts for bromination of alkenes

D. C. Braddock, G. Cansell and S. A. Hermitage, Chem. Commun., 2006, 2483 DOI: 10.1039/B604130B

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