Issue 23, 2006
From the journal:

Chemical Communications

α-Substituted acylsilanes via a highly selective [1,4]-Wittig rearrangement of α-benzyloxyallylsilane†

Edith N. Onyeozilia  and  Robert E. Maleczka Jr.*a  

* Corresponding authors

a Department of Chemistry, Michigan State University, 540 Chemistry, East Lansing, Michigan, USA
E-mail: maleczka@chemistry.msu.edu
Fax: +1 517 353 1793
Tel: +1 517 355 9715

Abstract

α-Benzyloxyallylsilane undergoes efficient [1,4]-Wittig rearrangement to generate an enolate intermediate that can be trapped with various electrophiles, thereby providing a new synthetic approach to substituted acylsilanes.

Graphical abstract: α-Substituted acylsilanes via a highly selective [1,4]-Wittig rearrangement of α-benzyloxyallylsilane

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Article information

DOI
https://doi.org/10.1039/B603228A
Article type
Communication
Submitted
07 Mar 2006
Accepted
11 Apr 2006
First published
03 May 2006

Chem. Commun., 2006, 2466-2468

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α-Substituted acylsilanes via a highly selective [1,4]-Wittig rearrangement of α-benzyloxyallylsilane

E. N. Onyeozili and R. E. Maleczka Jr., Chem. Commun., 2006, 2466 DOI: 10.1039/B603228A

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