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Issue 19, 2006
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The pentanuclear Feii cluster [(C5H4)6Fe5]2−: bringing together ferrocene sandwiches and homoleptic Feii-cyclopentadienyl σ-complexes

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Abstract

Reaction of [(fc)3(Li)6·(TMEDA)2] with FeCl2 gives the pentanuclear iron complex [(fc)3(Fe)2(Li)2·(TMEDA)2] featuring two ferra[1]ferrocenophane moieties bridged by a 1,1′-ferrocenediyl unit; the non-ferrocene FeII ions are tetra-coordinate and adopt a high-spin state.

Graphical abstract: The pentanuclear Feii cluster [(C5H4)6Fe5]2−: bringing together ferrocene sandwiches and homoleptic Feii-cyclopentadienyl σ-complexes

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Supplementary files

Article information


Submitted
16 Feb 2006
Accepted
24 Mar 2006
First published
07 Apr 2006

Chem. Commun., 2006, 2027-2029
Article type
Communication

The pentanuclear FeII cluster [(C5H4)6Fe5]2−: bringing together ferrocene sandwiches and homoleptic FeII-cyclopentadienyl σ-complexes

I. Sänger, J. B. Heilmann, M. Bolte, H. Lerner and M. Wagner, Chem. Commun., 2006, 2027
DOI: 10.1039/B602359B

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