Issue 21, 2006

Chiral diphosphites and diphosphoramidites as cheap and efficient ligands in Rh-catalyzed asymmetric olefinhydrogenation

Abstract

Chiral diphosphites and diphosphoramidites derived from BINOL or diphenylprolinol are efficient ligands in asymmetric Rh-catalyzed olefin hydrogenation, provided the proper achiral backbone is chosen.

Graphical abstract: Chiral diphosphites and diphosphoramidites as cheap and efficient ligands in Rh-catalyzed asymmetric olefin hydrogenation

Article information

Article type
Communication
Submitted
03 Feb 2006
Accepted
05 Apr 2006
First published
02 May 2006

Chem. Commun., 2006, 2292-2294

Chiral diphosphites and diphosphoramidites as cheap and efficient ligands in Rh-catalyzed asymmetric olefin hydrogenation

M. T. Reetz, G. Mehler and O. Bondarev, Chem. Commun., 2006, 2292 DOI: 10.1039/B601638C

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