Issue 18, 2006
From the journal:

Chemical Communications

Hydroxyl-directed dinitration of carboxylate ligands mediated by lead and nickel nitrates and preparation of Pb/Ni heterometallic complexes under hydrothermal conditions†

Xiaoju Li,ab   Rong Cao,*a   Zhengang Guoab  and  Jian Lüab  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fujian, Fuzhou, P. R. China
E-mail: rcao@ms.fjirsm.ac.cn
Fax: +86-591-83796710
Tel: +86-591-83714946

b Graduate School of the Chinese Academy of Science, Beijing, P. R. China

Abstract

The hydrothermal reaction of 5-hydroxyisophthalic acid (H3L) and lead and nickel nitrates produced a heterometallic polymer [Pb6Ni(μ3-OH)8(La)2]n containing heptanuclear [Pb6Ni(μ3-OH)8]6+ units and a homometallic complex {[Pb(Lb)(H2O)]·(H2O)0.25}n consisting of one-dimensional lead-oxide chains: evidently, the La and Lb ligands resulted from in situ hydroxyl-directed dinitration of L ligand during the hydrothermal reaction.

Graphical abstract: Hydroxyl-directed dinitration of carboxylate ligands mediated by lead and nickel nitrates and preparation of Pb/Ni heterometallic complexes under hydrothermal conditions

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Article information

DOI
https://doi.org/10.1039/B600684A
Article type
Communication
Submitted
18 Jan 2006
Accepted
06 Mar 2006
First published
29 Mar 2006

Chem. Commun., 2006, 1938-1940

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Hydroxyl-directed dinitration of carboxylate ligands mediated by lead and nickel nitrates and preparation of Pb/Ni heterometallic complexes under hydrothermal conditions

X. Li, R. Cao, Z. Guo and J. Lü, Chem. Commun., 2006, 1938 DOI: 10.1039/B600684A

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