Issue 20, 2006

Sandwich-shaped silver(i) metallomacrocycles encapsulating a XF62− (X = Si, Ge and Sn) anion

Abstract

A series of sandwich-shaped complexes based on two square tetranuclear Ag(I) metallomacrocycles, {[Ag4(pprd)4]2(XF6)}-(BF4)6·8MeNO2 (pprd = 4-(2-pyridyl)pyrimidine; X = Si, Ge and Sn), in which a XF62− anion is encapsulated, were prepared and their structures were characterized both in the solid state and solution.

Graphical abstract: Sandwich-shaped silver(i) metallomacrocycles encapsulating a XF62− (X = Si, Ge and Sn) anion

Supplementary files

Article information

Article type
Communication
Submitted
04 Jan 2006
Accepted
06 Mar 2006
First published
17 Mar 2006

Chem. Commun., 2006, 2161-2163

Sandwich-shaped silver(I) metallomacrocycles encapsulating a XF62− (X = Si, Ge and Sn) anion

M. Maekawa, S. Kitagawa, T. Kuroda-Sowa and M. Munakata, Chem. Commun., 2006, 2161 DOI: 10.1039/B518411H

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