Issue 1, 2006
From the journal:

Chemical Communications

Non-covalent expansion of an organic bilayer involving exo-cavity interplay of tetraphenylphosphonium with para-sulfonato-calix[4]arene

Mohamed Makha,a   Alexandre N. Soboleva  and  Colin L. Raston*a  

* Corresponding authors

a Chemistry M313, School of Biomedical, Biomolecular and Chemical Sciences, University of Western Australia, Crawley, Perth, Australia
E-mail: clraston@chem.uwa.edu.au
Fax: (+61) 8 6488 1005

Abstract

Reaction of equimolar amounts of sodium para-sulfonato-calix[4]arene, tetraphenylphosphonium chloride and ytterbium chloride in water results in the formation of a mineral clay-like structure, where the hydrophobic tetraphenylphosphonium cations interpose a bilayer arrangement based on a 2D coordination polymer of (calix[4]arene)5−/Na+/Yb3+.

Graphical abstract: Non-covalent expansion of an organic bilayer involving exo-cavity interplay of tetraphenylphosphonium with para-sulfonato-calix[4]arene

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Article information

DOI
https://doi.org/10.1039/B513543E
Article type
Communication
Submitted
22 Sep 2005
Accepted
10 Oct 2005
First published
16 Nov 2005

Chem. Commun., 2006, 57-59

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Non-covalent expansion of an organic bilayer involving exo-cavity interplay of tetraphenylphosphonium with para-sulfonato-calix[4]arene

M. Makha, A. N. Sobolev and C. L. Raston, Chem. Commun., 2006, 57 DOI: 10.1039/B513543E

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