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Issue 4, 2006
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Syntheses and structures of new diaryl lead(ii) compounds PbR2 (1, R = 2,4,6-triphenylphenyl; 2, R = 2,6-bis(1′-naphthyl)phenyl)

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Abstract

Reaction of RLi with lead(II) bromide affords the diaryl lead(II) compounds PbR2 (R1 = 2,4,6-triphenylphenyl, 1; R2 = 2,6-bis(1′-naphthyl)phenyl, 2), which have monomeric, carbene-like structures with bent two-coordinate Pb(II) centers.

Graphical abstract: Syntheses and structures of new diaryl lead(ii) compounds PbR2 (1, R = 2,4,6-triphenylphenyl; 2, R = 2,6-bis(1′-naphthyl)phenyl)

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Submitted
20 Sep 2005
Accepted
20 Oct 2005
First published
06 Dec 2005

Chem. Commun., 2006, 403-405
Article type
Communication

Syntheses and structures of new diaryl lead(II) compounds PbR2 (1, R = 2,4,6-triphenylphenyl; 2, R = 2,6-bis(1′-naphthyl)phenyl)

X. Yang, Y. Wang, P. Wei, B. Quillian and G. H. Robinson, Chem. Commun., 2006, 403
DOI: 10.1039/B513401C

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