Issue 45, 2005
From the journal:

Chemical Communications

Merging homogeneous catalysis with biocatalysis; papain as hydrogenation catalyst†

Lavinia Panella,a   Jaap Broos,b   Jianfeng Jin,b   Marco W. Fraaije,b   Dick B. Janssen,b   Margot Jeronimus-Stratingh,c   Ben L. Feringa,a   Adriaan J. Minnaarda  and  Johannes G. de Vries*ad  

* Corresponding authors

a Department of Organic & Molecular Inorganic Chemistry, University of Groningen, Nijenborgh 4, Groningen, The Netherlands

b Department of Biochemistry, University of Groningen, Nijenborgh 4, Groningen, The Netherlands

c Faculty Centre for Mass Spectrometry, University of Groningen, Antonius Deusinglaan 1, Groningen, The Netherlands

d DSM Research, Life Sciences—Advanced Synthesis & Catalysis, P. O. Box 18, Geleen, The Netherlands
E-mail: Hans-JG.Vries-de@dsm.com

Abstract

Papain, modified at Cys-25 with a monodentate phosphite ligand and complexed with Rh(COD)2BF4, is an active catalyst in the hydrogenation of methyl 2-acetamidoacrylate.

Graphical abstract: Merging homogeneous catalysis with biocatalysis; papain as hydrogenation catalyst

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Article information

DOI
https://doi.org/10.1039/B512138H
Article type
Communication
Submitted
30 Aug 2005
Accepted
16 Sep 2005
First published
14 Oct 2005

Chem. Commun., 2005, 5656-5658

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Merging homogeneous catalysis with biocatalysis; papain as hydrogenation catalyst

L. Panella, J. Broos, J. Jin, M. W. Fraaije, D. B. Janssen, M. Jeronimus-Stratingh, B. L. Feringa, A. J. Minnaard and J. G. de Vries, Chem. Commun., 2005, 5656 DOI: 10.1039/B512138H

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