Issue 47, 2005

Latent reactive groups unveiled through equilibrium dynamics and exemplified in crosslinking during film formation from aqueous polymer colloids

Abstract

The concept of using equilibrium dynamics to provide for both protection and unveiling of latent functional groups at appropriate times in aqueous polymer colloid coatings designed for crosslinking only during film formation is introduced; the new functional monomer, 4-hydroxyethylsulfonylstyrene (HESS), readily undergoes emulsion copolymerization with acrylates to form stable latexes, followed by crosslinking by loss of water during film formation.

Graphical abstract: Latent reactive groups unveiled through equilibrium dynamics and exemplified in crosslinking during film formation from aqueous polymer colloids

Supplementary files

Article information

Article type
Communication
Submitted
25 Aug 2005
Accepted
28 Sep 2005
First published
20 Oct 2005

Chem. Commun., 2005, 5904-5906

Latent reactive groups unveiled through equilibrium dynamics and exemplified in crosslinking during film formation from aqueous polymer colloids

D. J. Berrisford, P. A. Lovell, N. R. Suliman and A. Whiting, Chem. Commun., 2005, 5904 DOI: 10.1039/B512073J

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