Issue 47, 2005

Samarium versus aluminium Lewis acidity in a mixed alkyl carboxylate complex related to alkylaluminium activation in diene polymerization catalysis

Abstract

[(C5Me5)2Sm(μ-O2CPh)]2 reacts with iBu3Al to form a mixed bridge samarium aluminium complex [(C5Me5)2Sm(μ-O2CPh)(μ-iBu)Al(iBu)2], that displays two different carboxylate orientations toward the metals in a single crystal.

Graphical abstract: Samarium versus aluminium Lewis acidity in a mixed alkyl carboxylate complex related to alkylaluminium activation in diene polymerization catalysis

Supplementary files

Article information

Article type
Communication
Submitted
18 Aug 2005
Accepted
23 Sep 2005
First published
21 Oct 2005

Chem. Commun., 2005, 5925-5927

Samarium versus aluminium Lewis acidity in a mixed alkyl carboxylate complex related to alkylaluminium activation in diene polymerization catalysis

W. J. Evans, T. M. Champagne and J. W. Ziller, Chem. Commun., 2005, 5925 DOI: 10.1039/B511714C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements