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Issue 43, 2005
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Samarium diiodide-induced intramolecular pinacol coupling of dinitrones: synthesis of cyclic cis-vicinal diamines

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Abstract

Pinacol coupling of alkyl dinitrones mediated by SmI2 was achieved in the presence of a proton source allowing the synthesis of cyclic vicinal diamines with good cis-selectivity.

Graphical abstract: Samarium diiodide-induced intramolecular pinacol coupling of dinitrones: synthesis of cyclic cis-vicinal diamines

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Supplementary files

Article information


Submitted
11 Aug 2005
Accepted
09 Sep 2005
First published
30 Sep 2005

Chem. Commun., 2005, 5402-5404
Article type
Communication

Samarium diiodide-induced intramolecular pinacol coupling of dinitrones: synthesis of cyclic cis-vicinal diamines

J. Ebran, R. G. Hazell and T. Skrydstrup, Chem. Commun., 2005, 5402
DOI: 10.1039/B511491H

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