Substituted m-phenylene bridges as strong ferromagnetic couplers for CuII–bridge–CuII magnetic interactions: new perspectives

Alok Ranjan Paital; Tamoghna Mitra; Debashis Ray; Wing Tak Wong; Jordi Ribas-Ariño; Juan J. Novoa; Joan Ribas; Guillem Aromí

doi:10.1039/B510074G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Substituted m-phenylene bridges as strong ferromagnetic couplers for Cuⁱⁱ–bridge–Cuⁱⁱ magnetic interactions: new perspectives†

Alok Ranjan Paital,^b Tamoghna Mitra,^b Debashis Ray,*^b Wing Tak Wong,^c Jordi Ribas-Ariño,^d Juan J. Novoa,^d Joan Ribas^a and Guillem Aromí*^a

Author affiliations

* Corresponding authors

^a Departament de Química Inorgànica, Universitat de Barcelona, Diagonal, 647 08028-Barcelona, Spain
E-mail: guillem.aromi@qi.ub.es
Fax: +34 93 490 7725
Tel: +34 93 402 1271

^b Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302, India
E-mail: dray@chem.iitkgp.ernet.in
Fax: 91-3222-82252
Tel: 03222-283324

^c Department of Chemistry, University of Hong Kong, Pokfulam Road, Pokfulam, Hong Kong SAR, P. R. China
E-mail: wtwong@hkucc.hku.hk
Fax: 852-2547-2933
Tel: 852-2859-7914

^d Departament de Química Física and CERQT, Universitat de Barcelona, Diagonal, 647 08028-Barcelona, Spain

Abstract

Based on a combined theoretical–experimental study, we propose that substituted m-phenylene ligands (m-N-Φ-N) can act as tuneable strong ferromagnetic couplers connecting Cu^II ions; a new complex presenting that bridge with J close to +15 cm⁻¹ has been suggested and synthesized.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B510074G
Article type: Communication
Submitted: 19 Jul 2005
Accepted: 31 Aug 2005
First published: 13 Sep 2005

Download Citation

Chem. Commun., 2005, 5172-5174

Permissions

Request permissions

Substituted m-phenylene bridges as strong ferromagnetic couplers for Cu^II–bridge–Cu^II magnetic interactions: new perspectives

A. R. Paital, T. Mitra, D. Ray, W. T. Wong, J. Ribas-Ariño, J. J. Novoa, J. Ribas and G. Aromí, Chem. Commun., 2005, 5172 DOI: 10.1039/B510074G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications