Issue 43, 2005

Non-stoichiometry induced by differential oxygen/lone pair occupation in chiral bicyclic 1,1′-binaphthoxy cyclodiphosphazanes

Abstract

Non-stoichiometry and isostructurality in a set of chiral phosphorus compounds as a result of lone pair/oxygen exchange, substantiated by the combined use of 31P NMR spectroscopy and X-ray crystallography, is described.

Graphical abstract: Non-stoichiometry induced by differential oxygen/lone pair occupation in chiral bicyclic 1,1′-binaphthoxy cyclodiphosphazanes

Supplementary files

Article information

Article type
Communication
Submitted
05 Jul 2005
Accepted
08 Sep 2005
First published
03 Oct 2005

Chem. Commun., 2005, 5396-5398

Non-stoichiometry induced by differential oxygen/lone pair occupation in chiral bicyclic 1,1′-binaphthoxy cyclodiphosphazanes

M. Chakravarty, P. Kommana and K. C. K. Swamy, Chem. Commun., 2005, 5396 DOI: 10.1039/B509327A

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