Issue 43, 2005

[Bi6F11]7+—an unusual, highly charged bismuth fluoro complex in (Se4)[Bi6F11][AsF6]9·10 SO2

Abstract

A unique, highly charged cationic bismuth fluoro cluster [Bi6F11]7+, embedded in the complex crystal structure of (Se4)2+[Bi6F11]7+[AsF6]9·10 SO2, was synthesized from Bi2Se3 and AsF5 in liquid SO2.

Graphical abstract: [Bi6F11]7+—an unusual, highly charged bismuth fluoro complex in (Se4)[Bi6F11][AsF6]9·10 SO2

Supplementary files

Article information

Article type
Communication
Submitted
23 Jun 2005
Accepted
09 Sep 2005
First published
04 Oct 2005

Chem. Commun., 2005, 5453-5455

[Bi6F11]7+—an unusual, highly charged bismuth fluoro complex in (Se4)[Bi6F11][AsF6]9·10 SO2

J. Beck and F. Steden, Chem. Commun., 2005, 5453 DOI: 10.1039/B508898D

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