Issue 37, 2005
From the journal:

Chemical Communications

Crystal structures and magnetic properties of a sterically encumbered dithiadiazolyl radical, 2,4,6-(F3C)3C6H2CNSSN˙

Antonio Alberola,a   Caroline S. Clarke,a   Delia A. Haynes,a   Sofia I. Pascua  and  Jeremy M. Rawson*a  

* Corresponding authors

a Department of Chemistry, The University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: jmr31@cus.cam.ac.uk

Abstract

The sterically protected dithiadiazolyl radical (F3C)3C6H2CNSSN˙ (1) crystallises in two polymorphs: 1α, comprised of monomeric units and 1β, containing a mixture of both π*–π* dimers and S = ½ monomers; whilst both polymorphs exhibit similar structure-directing motifs, the variation in packing leads to different magnetic behaviour.

Graphical abstract: Crystal structures and magnetic properties of a sterically encumbered dithiadiazolyl radical, 2,4,6-(F3C)3C6H2CNSSN˙

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Article information

DOI
https://doi.org/10.1039/B508371K
Article type
Communication
Submitted
14 Jun 2005
Accepted
01 Aug 2005
First published
25 Aug 2005

Chem. Commun., 2005, 4726-4728

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Crystal structures and magnetic properties of a sterically encumbered dithiadiazolyl radical, 2,4,6-(F3C)3C6H2CNSSN˙

A. Alberola, C. S. Clarke, D. A. Haynes, S. I. Pascu and J. M. Rawson, Chem. Commun., 2005, 4726 DOI: 10.1039/B508371K

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