Issue 43, 2005
From the journal:

Chemical Communications

Four-electron reduction of dinitrogen during solution disproportionation of the organodimetallic (η-C5Me4R)2Ta2(μ-Cl)4 (R = Me, Et) to a new μ-η1,η1-N2 complex and odd-electron organotrimetallic cluster

Ting-Yu Lee,a   Alfred J. Wooten,a   Jeffrey J. Luci,a   Dale C. Swensona  and  Louis Messerle*a  

* Corresponding authors

a Department of Chemistry, The University of Iowa, Iowa City, Iowa, USA
E-mail: lou-messerle@uiowa.edu
Fax: (319) 335-1270
Tel: (319) 335-1372

Abstract

(C5Me5R)2Ta2Cl4 (d2–d2) disproportionates under dinitrogen to [(C5Me4R)TaCl2]2(μ-N2) and the D3h cluster cation (C5Me4R)3Ta3(μ-Cl)6+ with anionic (C5Me4R)TaCl4−.

Graphical abstract: Four-electron reduction of dinitrogen during solution disproportionation of the organodimetallic (η-C5Me4R)2Ta2(μ-Cl)4 (R = Me, Et) to a new μ-η1,η1-N2 complex and odd-electron organotrimetallic cluster

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Article information

DOI
https://doi.org/10.1039/B508148C
Article type
Communication
Submitted
08 Jun 2005
Accepted
03 Aug 2005
First published
04 Oct 2005

Chem. Commun., 2005, 5444-5446

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Four-electron reduction of dinitrogen during solution disproportionation of the organodimetallic (η-C5Me4R)2Ta2(μ-Cl)4 (R = Me, Et) to a new μ-η1,η1-N2 complex and odd-electron organotrimetallic cluster

T. Lee, A. J. Wooten, J. J. Luci, D. C. Swenson and L. Messerle, Chem. Commun., 2005, 5444 DOI: 10.1039/B508148C

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