Issue 32, 2005

Total synthesis of buergerinin F via effective construction of the asymmetric quaternary carbons using an enantioselective aldol reaction

Abstract

An efficient method for the synthesis of (+)-buergerinin F is established via the enantioselective aldol reaction of a tetrasubstituted ketene silyl acetal with crotonaldehyde, followed by intramolecular Wacker-type ketalization.

Graphical abstract: Total synthesis of buergerinin F via effective construction of the asymmetric quaternary carbons using an enantioselective aldol reaction

Supplementary files

Article information

Article type
Communication
Submitted
26 May 2005
Accepted
17 Jun 2005
First published
14 Jul 2005

Chem. Commun., 2005, 4062-4064

Total synthesis of buergerinin F via effective construction of the asymmetric quaternary carbons using an enantioselective aldol reaction

I. Shiina, Y. Kawakita, R. Ibuka, K. Yokoyama and Y. Yamai, Chem. Commun., 2005, 4062 DOI: 10.1039/B507401K

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