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Issue 32, 2005
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Total synthesis of buergerinin F via effective construction of the asymmetric quaternary carbons using an enantioselective aldol reaction

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Abstract

An efficient method for the synthesis of (+)-buergerinin F is established via the enantioselective aldol reaction of a tetrasubstituted ketene silyl acetal with crotonaldehyde, followed by intramolecular Wacker-type ketalization.

Graphical abstract: Total synthesis of buergerinin F via effective construction of the asymmetric quaternary carbons using an enantioselective aldol reaction

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Article information


Submitted
26 May 2005
Accepted
17 Jun 2005
First published
14 Jul 2005

Chem. Commun., 2005, 4062-4064
Article type
Communication

Total synthesis of buergerinin F via effective construction of the asymmetric quaternary carbons using an enantioselective aldol reaction

I. Shiina, Y. Kawakita, R. Ibuka, K. Yokoyama and Y. Yamai, Chem. Commun., 2005, 4062
DOI: 10.1039/B507401K

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