Issue 32, 2005
From the journal:

Chemical Communications

Demethylation of the [Me3Sn(PhN2O2)]4 tetramer into dimeric [Me2Sn(PhN2O2)2]2: a thermally induced methyl-transfer between supramolecules†‡

Andrea Deák*a  and  Gábor Tárkányia  

* Corresponding authors

a Institute of Structural Chemistry, Chemical Research Center, Hungarian Academy of Sciences, P. O. Box 17, Budapest, Hungary
E-mail: deak@chemres.hu
Fax: 00-36-1-438-4141/201
Tel: 00-36-1-325-7547

Abstract

The single crystals of tetrameric [Me3Sn(PhN2O2)]4 (1) supramolecule demethylates into single crystals of [Me2Sn(PhN2O2)2]2 dimer (2) and volatile Me4Sn, as a result of a crystal-to-crystal supramolecular structural transformation, which occurs upon heating and it is accompanied by a significant change of the molecular and crystal structures.

Graphical abstract: Demethylation of the [Me3Sn(PhN2O2)]4 tetramer into dimeric [Me2Sn(PhN2O2)2]2: a thermally induced methyl-transfer between supramolecules

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Article information

DOI
https://doi.org/10.1039/B506728F
Article type
Communication
Submitted
12 May 2005
Accepted
14 Jun 2005
First published
15 Jul 2005

Chem. Commun., 2005, 4074-4076

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Demethylation of the [Me3Sn(PhN2O2)]4 tetramer into dimeric [Me2Sn(PhN2O2)2]2: a thermally induced methyl-transfer between supramolecules

A. Deák and G. Tárkányi, Chem. Commun., 2005, 4074 DOI: 10.1039/B506728F

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