Issue 35, 2005
From the journal:

Chemical Communications

Radical-carbanion cyclo-coupling in armed aromatics: overriding steric hindrance to ring closure

Mark D. Roydhousea  and  John C. Walton*a  

* Corresponding authors

a University of St. Andrews, School of Chemistry, EaStCHEM, St. Andrews, Fife, UK
E-mail: jcw@st-and.ac.uk
Fax: 44 (0)1334 463808
Tel: 44 (0)1334 463864

Abstract

ω-(2-Halophenyl)alkyl-2-oxazolines were prepared and reacted via base promoted intramolecular coupling of radical with carbanionic centres to yield 1-phenyl-1-oxazolino-indan and -tetralin derivatives containing quaternary C-atoms.

Graphical abstract: Radical-carbanion cyclo-coupling in armed aromatics: overriding steric hindrance to ring closure

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Article information

DOI
https://doi.org/10.1039/B506391D
Article type
Communication
Submitted
06 May 2005
Accepted
12 Jul 2005
First published
04 Aug 2005

Chem. Commun., 2005, 4453-4455

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Radical-carbanion cyclo-coupling in armed aromatics: overriding steric hindrance to ring closure

M. D. Roydhouse and J. C. Walton, Chem. Commun., 2005, 4453 DOI: 10.1039/B506391D

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