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Issue 31, 2005
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Stable spirocyclic neutral radicals: aluminium and gallium boraamidinates

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Abstract

Stable dark red (M = Al) or dark green (M = Ga) neutral radicals {[PhB(μ-NtBu)2]2M}˙ are obtained by the oxidation of their corresponding anions with iodine, and EPR spectra supported by DFT calculations show that the spin density is equally delocalized over all four nitrogen atoms in these spiroconjugated systems.

Graphical abstract: Stable spirocyclic neutral radicals: aluminium and gallium boraamidinates

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Supplementary files

Article information


Submitted
05 May 2005
Accepted
02 Jun 2005
First published
11 Jul 2005

Chem. Commun., 2005, 3930-3932
Article type
Communication

Stable spirocyclic neutral radicals: aluminium and gallium boraamidinates

T. Chivers, D. J. Eisler, C. Fedorchuk, G. Schatte, H. M. Tuononen and R. T. Boeré, Chem. Commun., 2005, 3930
DOI: 10.1039/B506253E

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