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Issue 29, 2005
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A chiral porous 3D metal–organic framework with an unprecedented 4-connected network topology

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Abstract

A novel homochiral 3D metal–organic framework [CdL2(H2O)2][ClO4]2·2DMF·3EtOH·5/3H2O, 1, (L = (R)-6,6′-dichloro-2,2′-diethoxy-1,1′-binaphthyl-4,4′-bipyridine) exhibits an unprecedented 4-connected network topology owing to the cis- configuration of the Cd coordination and possesses permanent porosity as demonstrated by TGA, XRPD, and CO2 adsorption isotherm studies.

Graphical abstract: A chiral porous 3D metal–organic framework with an unprecedented 4-connected network topology

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Publication details

The article was received on 26 Apr 2005, accepted on 25 May 2005 and first published on 15 Jun 2005


Article type: Communication
DOI: 10.1039/B505916J
Chem. Commun., 2005, 3673-3675

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    A chiral porous 3D metal–organic framework with an unprecedented 4-connected network topology

    C. Wu and W. Lin, Chem. Commun., 2005, 3673
    DOI: 10.1039/B505916J

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