Issue 33, 2005
From the journal:

Chemical Communications

Analysis of key steps in the catalytic cross-coupling of alkyl electrophiles under Negishi-like conditions†

Gavin D. Jones,a   Chris McFarland,a   Thomas J. Andersona  and  David A. Vicic*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Arkansas, Fayetteville, USA
E-mail: dvicic@uark.edu
Fax: +1 479 575 4049
Tel: +1 479 575 5078

Abstract

The use of tpy′ (tpy′ = 4,4′,4″-tri-tert-butyl-terpyridine) as a ligand for nickel allows for the isolation of a Ni(I)–alkyl complex and a Ni(II)–alkyl halide complex, both of which can be used as mechanistic probes of key steps in alkyl cross-coupling reactions.

Graphical abstract: Analysis of key steps in the catalytic cross-coupling of alkyl electrophiles under Negishi-like conditions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B504996B
Article type
Communication
Submitted
08 Apr 2005
Accepted
24 Jun 2005
First published
22 Jul 2005

Chem. Commun., 2005, 4211-4213

Permissions

Request permissions

Analysis of key steps in the catalytic cross-coupling of alkyl electrophiles under Negishi-like conditions

G. D. Jones, C. McFarland, T. J. Anderson and D. A. Vicic, Chem. Commun., 2005, 4211 DOI: 10.1039/B504996B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements