Issue 25, 2005
From the journal:

Chemical Communications

New routes to manganese higher-nuclearity topologies: synthesis of the cluster [Mn8(μ4-O)4(phpz)8(thf)4]

Stefania Tanase,a   Guillem Aromí,b   Elisabeth Bouwman,a   Huub Kooijman,c   Anthony L. Spekc  and  Jan Reedijk*a  

* Corresponding authors

a Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, PO Box 9502, Leiden, The Netherlands
E-mail: reedijk@chem.leidenuniv.nl
Fax: +31 71-527-4671

b Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 647, 08028 Barcelona, Spain

c Bijvoet Center for Biomolecular Research, Utrecht University, Padualaan 8, Utrecht, The Netherlands

Abstract

Reaction of Mn(ClO4)2·6H2O with 3(5)-methyl-5(3)-(2-hydroxyphenyl)pyrazole (H2phpz) affords a highly asymmetric octanuclear manganese(III) cluster resulting from the different bridging coordination modes of the ligand H2phpz.

Graphical abstract: New routes to manganese higher-nuclearity topologies: synthesis of the cluster [Mn8(μ4-O)4(phpz)8(thf)4]

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Article information

DOI
https://doi.org/10.1039/B504215A
Article type
Communication
Submitted
24 Mar 2005
Accepted
22 Apr 2005
First published
18 May 2005

Chem. Commun., 2005, 3147-3149

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New routes to manganese higher-nuclearity topologies: synthesis of the cluster [Mn8(μ4-O)4(phpz)8(thf)4]

S. Tanase, G. Aromí, E. Bouwman, H. Kooijman, A. L. Spek and J. Reedijk, Chem. Commun., 2005, 3147 DOI: 10.1039/B504215A

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