Issue 25, 2005

New routes to manganese higher-nuclearity topologies: synthesis of the cluster [Mn84-O)4(phpz)8(thf)4]

Abstract

Reaction of Mn(ClO4)2·6H2O with 3(5)-methyl-5(3)-(2-hydroxyphenyl)pyrazole (H2phpz) affords a highly asymmetric octanuclear manganese(III) cluster resulting from the different bridging coordination modes of the ligand H2phpz.

Graphical abstract: New routes to manganese higher-nuclearity topologies: synthesis of the cluster [Mn8(μ4-O)4(phpz)8(thf)4]

Supplementary files

Article information

Article type
Communication
Submitted
24 Mar 2005
Accepted
22 Apr 2005
First published
18 May 2005

Chem. Commun., 2005, 3147-3149

New routes to manganese higher-nuclearity topologies: synthesis of the cluster [Mn84-O)4(phpz)8(thf)4]

S. Tanase, G. Aromí, E. Bouwman, H. Kooijman, A. L. Spek and J. Reedijk, Chem. Commun., 2005, 3147 DOI: 10.1039/B504215A

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