Issue 27, 2005
From the journal:

Chemical Communications

New diphosphine ligands based on diphenyl ether for the Pd-catalyzed CO/ethene copolymerization†

Maria Caporali,a   Christian Müller,a   Bastiaan B. P. Staal,a   Duncan M. Tooke,b   Anthony L. Spekb  and  Piet W. N. M. van Leeuwen*a  

* Corresponding authors

a Department of Chemical Engineering and Chemistry, Technische Universiteit Eindhoven, P.O. Box 513, Eindhoven, The Netherlands
E-mail: p.w.n.m.v.leeuwen@tue.nl
Fax: +31 40 245 5054
Tel: +31 40 247 3040

b Bijvoet Center for Biomolecular Research, Dept. Crystal and Structural Chemistry, Utrecht University, Utrecht, The Netherlands

Abstract

The catalytic activity and selectivity of palladium(II) complexes of new, flexible bidentate ligands in the CO/ethene copolymerization reaction have been found to change considerably with the steric properties of the ligands.

Graphical abstract: New diphosphine ligands based on diphenyl ether for the Pd-catalyzed CO/ethene copolymerization

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Article information

DOI
https://doi.org/10.1039/B503764F
Article type
Communication
Submitted
15 Mar 2005
Accepted
29 Apr 2005
First published
09 Jun 2005

Chem. Commun., 2005, 3478-3480

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New diphosphine ligands based on diphenyl ether for the Pd-catalyzed CO/ethene copolymerization

M. Caporali, C. Müller, B. B. P. Staal, D. M. Tooke, A. L. Spek and P. W. N. M. van Leeuwen, Chem. Commun., 2005, 3478 DOI: 10.1039/B503764F

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