Structures of a CO adlayer on a Pt(100) electrode in HClO4 solution studied by in situ STM

Mitsuru Wakisaka; Takaharu Ohkanda; Toshiki Yoneyama; Hiroyuki Uchida; Masahiro Watanabe

doi:10.1039/B503148F

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Structures of a CO adlayer on a Pt(100) electrode in HClO₄ solution studied by in situSTM

Mitsuru Wakisaka,^a Takaharu Ohkanda,^b Toshiki Yoneyama,^a Hiroyuki Uchida^b and Masahiro Watanabe*^a

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* Corresponding authors

^a Clean Energy Research Center, University of Yamanashi, 4 Takeda, Kofu 400-8510, Japan
E-mail: m-watanabe@yamanashi.ac.jp
Fax: +81-55-254-0371
Tel: +81-55-220-8620

^b Interdisciplinary Graduate School of Medicine and Engineering, University of Yamanashi, 4 Takeda, Kofu 400-8511, Japan
E-mail: h-uchida@ab11.yamanashi.ac.jp
Fax: +81-55-220-8619
Tel: +81-55-220-8619

Abstract

We have obtained the first in situ STM atomic images of a CO adlayer on a Pt(100)-(1 × 1) electrode in 0.1 M HClO₄ solution, exhibiting a phase transition from c(6 × 2)-10CO to c(4 × 2)-6CO at E > 0.3 V vs. RHE.

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Article information

DOI: https://doi.org/10.1039/B503148F
Article type: Communication
Submitted: 03 Mar 2005
Accepted: 24 Mar 2005
First published: 13 Apr 2005

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Chem. Commun., 2005, 2710-2712

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Structures of a CO adlayer on a Pt(100) electrode in HClO₄ solution studied by in situ STM

M. Wakisaka, T. Ohkanda, T. Yoneyama, H. Uchida and M. Watanabe, Chem. Commun., 2005, 2710 DOI: 10.1039/B503148F

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