Issue 25, 2005

Homoleptic uranium(iii) imidodiphosphinochalcogenides including the first structurally characterised molecular trivalent actinide–Se bond

Abstract

Preparation of U[N(EPPh2)2]3 (E = S or Se) by treating U[N(SiMe3)2]3 with three equivalents of NH(EPPh2)2 is described together with presentation of a hitherto unreported molecular crystal structure containing An(III)–Se bonds (An = actinide).

Graphical abstract: Homoleptic uranium(iii) imidodiphosphinochalcogenides including the first structurally characterised molecular trivalent actinide–Se bond

Supplementary files

Article information

Article type
Communication
Submitted
02 Mar 2005
Accepted
25 Apr 2005
First published
18 May 2005

Chem. Commun., 2005, 3215-3217

Homoleptic uranium(III) imidodiphosphinochalcogenides including the first structurally characterised molecular trivalent actinide–Se bond

A. J. Gaunt, B. L. Scott and M. P. Neu, Chem. Commun., 2005, 3215 DOI: 10.1039/B503106K

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