Issue 26, 2005
From the journal:

Chemical Communications

Reversible hydrogen gas uptake in nanoporous Prussian Blue analogues†

Karena W. Chapman,a   Peter D. Southon,a   Colin L. Weeksa  and  Cameron J. Kepert*a  

* Corresponding authors

a School of Chemistry, University of Sydney, NSW 2006, Australia
E-mail: c.kepert@chem.usyd.edu.au
Fax: +61 2 9351 3329
Tel: +61 2 9351 5741

Abstract

The family of dehydrated nanoporous Prussian Blue analogues, MII3[CoIII(CN)6]2 (MII = Mn, Fe, Co, Ni, Cu, Zn, Cd), which contain coordinatively unsaturated divalent metal cations, undergoes reversible sorption of hydrogen gas up to 1.2 wt% (at 77 K, 101.3 kPa), the capacity of which depends on the metal ion.

Graphical abstract: Reversible hydrogen gas uptake in nanoporous Prussian Blue analogues

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Article information

DOI
https://doi.org/10.1039/B502850G
Article type
Communication
Submitted
25 Feb 2005
Accepted
16 May 2005
First published
27 May 2005

Chem. Commun., 2005, 3322-3324

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Reversible hydrogen gas uptake in nanoporous Prussian Blue analogues

K. W. Chapman, P. D. Southon, C. L. Weeks and C. J. Kepert, Chem. Commun., 2005, 3322 DOI: 10.1039/B502850G

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