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Issue 20, 2005
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The rhodium catalyzed three-component reaction of diazoacetates, titanium(IV) alkoxides and aldehydes

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Abstract

The rhodium(II)-catalyzed three-component reaction of diazoacetates, titanium alkoxides and aldehydes is shown to give α-alkoxyl-β-hydroxyl acid derivatives; the novel C–C bond formation reaction is proposed to occur through oxonium ylides derived from diazo compounds and titanium alkoxides, and followed by intermolecular trapping by aldehydes.

Graphical abstract: The rhodium catalyzed three-component reaction of diazoacetates, titanium(iv) alkoxides and aldehydes

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Publication details

The article was received on 10 Feb 2005, accepted on 22 Mar 2005 and first published on 06 Apr 2005


Article type: Communication
DOI: 10.1039/B502093J
Citation: Chem. Commun., 2005,0, 2624-2626
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    The rhodium catalyzed three-component reaction of diazoacetates, titanium(IV) alkoxides and aldehydes

    C. Lu, H. Liu, Z. Chen, W. Hu and A. Mi, Chem. Commun., 2005, 0, 2624
    DOI: 10.1039/B502093J

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