Issue 19, 2005

Enantiospecific inclusion of chiral 1,2-dichloroethane rotamers in the crystal lattice of chiral square-pyramidal Cu(ii) complexes with perfectly polar alignment of guest and host molecules

Abstract

The inclusion compounds, [CuL12(H2O)]·(P)-C2H4Cl2 and [CuL22(H2O)]·(M)-C2H4Cl2 (HL1 = N-(2-hydroxy-5-nitrobenzyl)-(R)-α-methylbenzylamine and HL2 = N-(2-hydroxy-5-nitrobenzyl)-(S)-α-methylbenzylamine), crystallise in the non-centrosymmetric space group C2; intermolecular hydrogen bonding leads to a perfectly polar alignment of both host and guest molecules with enantioselectivity.

Graphical abstract: Enantiospecific inclusion of chiral 1,2-dichloroethane rotamers in the crystal lattice of chiral square-pyramidal Cu(ii) complexes with perfectly polar alignment of guest and host molecules

Supplementary files

Article information

Article type
Communication
Submitted
03 Feb 2005
Accepted
18 Mar 2005
First published
04 Apr 2005

Chem. Commun., 2005, 2515-2517

Enantiospecific inclusion of chiral 1,2-dichloroethane rotamers in the crystal lattice of chiral square-pyramidal Cu(II) complexes with perfectly polar alignment of guest and host molecules

V. K. Muppidi, P. S. Zacharias and S. Pal, Chem. Commun., 2005, 2515 DOI: 10.1039/B501642H

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