Isolation of axial conformers of chloro- and bromocyclohexane in a pure state as inclusion complexes with 9,9′-bianthryl, and the discovery of a novel 1,3 diaxial Cl⋯H weak interaction

Shinya Hirano; Shinji Toyota; Masako Kato; Fumio Toda

doi:10.1039/B501633A

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Isolation of axial conformers of chloro- and bromocyclohexane in a pure state as inclusion complexes with 9,9′-bianthryl, and the discovery of a novel 1,3 diaxial Cl⋯H weak interaction

Shinya Hirano,^a Shinji Toyota,^a Masako Kato*^b and Fumio Toda*^a

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* Corresponding authors

^a Department of Chemistry, Faculty of Science, Okayama University of Science, Ridai-cho 1-1, Japan
E-mail: toda@chem.ous.ac.jp
Fax: +81 86 256 9604
Tel: +81 86 256 9604

^b Division of Material Science, Graduate School of Humanities and Sciences, Nara Women's University, Nara 630-8506, Japan
E-mail: kato@cc.nara-wu.ac.jp

Abstract

The axial conformers of chloro- and bromocyclohexane were isolated in a pure state as inclusion complexes with 9,9′-bianthryl, and a 1,3 diaxial Cl⋯H weak interaction was discovered by X-ray analysis of the axial conformer of chlorocyclohexane.

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Supplementary files

Crystal structure data TXT (94K)

Article information

DOI: https://doi.org/10.1039/B501633A
Article type: Communication
Submitted: 03 Feb 2005
Accepted: 21 Apr 2005
First published: 18 May 2005

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Chem. Commun., 2005, 3646-3648

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Isolation of axial conformers of chloro- and bromocyclohexane in a pure state as inclusion complexes with 9,9′-bianthryl, and the discovery of a novel 1,3 diaxial Cl⋯H weak interaction

S. Hirano, S. Toyota, M. Kato and F. Toda, Chem. Commun., 2005, 3646 DOI: 10.1039/B501633A

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Chemical Communications

Isolation of axial conformers of chloro- and bromocyclohexane in a pure state as inclusion complexes with 9,9′-bianthryl, and the discovery of a novel 1,3 diaxial Cl⋯H weak interaction

Abstract

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Isolation of axial conformers of chloro- and bromocyclohexane in a pure state as inclusion complexes with 9,9′-bianthryl, and the discovery of a novel 1,3 diaxial Cl⋯H weak interaction

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