Issue 19, 2005
From the journal:

Chemical Communications

Benzene C–H activation by platinum(ii) complexes of bis(2-diphenylphosphinophenyl)amide†

Lan-Chang Liang,*a   Jia-Ming Lina  and  Wei-Ying Leea  

* Corresponding authors

a Department of Chemistry and Center for Nanoscience & Nanotechnology, National Sun Yat-sen University, Kaohsiung 80424, Taiwan
E-mail: lcliang@mail.nsysu.edu.tw
Fax: +886-7-5253908

Abstract

The amido diphosphine complexes [PNP]PtMe and [PNP]PtOTf, where [PNP]− is bis(2-diphenylphosphinophenyl)amide, effectively activate the benzene C–H bond in the presence of an appropriate Lewis acid or base, leading to the formation of [PNP]PtPh quantitatively.

Graphical abstract: Benzene C–H activation by platinum(ii) complexes of bis(2-diphenylphosphinophenyl)amide

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Article information

DOI
https://doi.org/10.1039/B501520K
Article type
Communication
Submitted
03 Feb 2005
Accepted
11 Mar 2005
First published
23 Mar 2005

Chem. Commun., 2005, 2462-2464

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Benzene C–H activation by platinum(II) complexes of bis(2-diphenylphosphinophenyl)amide

L. Liang, J. Lin and W. Lee, Chem. Commun., 2005, 2462 DOI: 10.1039/B501520K

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