Issue 17, 2005
From the journal:

Chemical Communications

Triple-stranded helices and zigzag chains of copper(i) 2-ethylimidazolate: solvent polarity-induced supramolecular isomerism†

Xiao-Chun Huang,ab   Jie-Peng Zhang,a   Yan-Yong Lina  and  Xiao-Ming Chen*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, China
E-mail: cescxm@zsu.edu.cn
Fax: +86 20 8411-2245
Tel: +86 20 8411-3986

b Department of Chemistry and Institute of Advanced Materials, Shantou University, Guangdong, China

Abstract

The solvent effect of different polarities in hydro(solvo)thermal reaction of CuII and 2-ethylimidazole leads to the generation of two supramolecular isomers of triple-stranded helical and zigzag chain-like structures of CuI 2-ethylimidazolate.

Graphical abstract: Triple-stranded helices and zigzag chains of copper(i) 2-ethylimidazolate: solvent polarity-induced supramolecular isomerism

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Article information

DOI
https://doi.org/10.1039/B501071C
Article type
Communication
Submitted
21 Jan 2005
Accepted
21 Feb 2005
First published
09 Mar 2005

Chem. Commun., 2005, 2232-2234

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Triple-stranded helices and zigzag chains of copper(I) 2-ethylimidazolate: solvent polarity-induced supramolecular isomerism

X. Huang, J. Zhang, Y. Lin and X. Chen, Chem. Commun., 2005, 2232 DOI: 10.1039/B501071C

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