Issue 17, 2005
From the journal:

Chemical Communications

Total synthesis of viridiofungin A†

Kenji Morokuma,a   Keisuke Takahashi,a   Jun Ishiharaa  and  Susumi Hatakeyama*a  

* Corresponding authors

a Graduate School of Biomedical Sciences, Nagasaki University, Nagasaki 852-8521, Japan
E-mail: susumi@net.nagasaki-u.ac.jp
Fax: +81-95-819-2426
Tel: +81-95-819-2426

Abstract

Viridiofungin A, a member of amino alkyl citrate antibiotics from Trichoderma viride, was enantioselectively synthesized in naturally occurring form for the first time, employing regio- and stereoselective opening of the chiral glycidate with vinylmagnesium bromide and alkene cross metathesis of the citric acid core and hexadec-15-en-8-one as key steps.

Graphical abstract: Total synthesis of viridiofungin A

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Article information

DOI
https://doi.org/10.1039/B500660K
Article type
Communication
Submitted
14 Jan 2005
Accepted
22 Feb 2005
First published
09 Mar 2005

Chem. Commun., 2005, 2265-2267

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Total synthesis of viridiofungin A

K. Morokuma, K. Takahashi, J. Ishihara and S. Hatakeyama, Chem. Commun., 2005, 2265 DOI: 10.1039/B500660K

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