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Issue 15, 2005
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New titanium and zirconium complexes with M–NH2 bonds formed by facile deprotonation of H3N·B(C6F5)3

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Abstract

Facile deprotonation of H3N·B(C6F5)3 with [M(NMe2)4] (M = Zr or Ti) yields the novel amidoborate complexes [Zr(NMe2)3{NH2B(C6F5)3}(HNMe2)] and [Ti(NMe2)3{NH2B(C6F5)3}].

Graphical abstract: New titanium and zirconium complexes with M–NH2 bonds formed by facile deprotonation of H3N·B(C6F5)3

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Publication details

The article was received on 13 Jan 2005, accepted on 16 Feb 2005 and first published on 01 Mar 2005


Article type: Communication
DOI: 10.1039/B500407A
Chem. Commun., 2005, 2044-2046

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    New titanium and zirconium complexes with M–NH2 bonds formed by facile deprotonation of H3N·B(C6F5)3

    A. J. Mountford, W. Clegg, R. W. Harrington, S. M. Humphrey and S. J. Lancaster, Chem. Commun., 2005, 2044
    DOI: 10.1039/B500407A

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